Phase Transitions in Complex Fluids

This important and timely book deals with the theoretical and experimental investigation of the phase transitions which occur in complex fluid systems, namely lyotropic systems, microemulsions, colloids, gels, polymers, biological membranes, Langmuir monolayers, and ferrofluids. It contains 20-odd review papers from the major contributors to this rapidly growing field of research, summarizing the main results obtained in the description and understanding of the phase transitions taking place between the isotopic, nematic, cholesteric, lamellar, hexagonal, and cubic mesophases of complex fluids.

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Complex fluids

This book presents a comprehensive overview of the modeling of complex fluids, including many common substances, such as toothpaste, hair gel, mayonnaise, liquid foam, cement and blood, which cannot be described by Navier-Stokes equations. It also offers an up-to-date mathematical and numerical analysis of the corresponding equations, as well as several practical numerical algorithms and software solutions for the approximation of the solutions. It discusses industrial (molten plastics, forming process), geophysical (mud flows, volcanic lava, glaciers and snow avalanches), and biological (blood flows, tissues) modeling applications. This book is a valuable resource for undergraduate students and researchers in applied mathematics, mechanical engineering and physics.

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Rheology of Complex Fluids

The aim of the School on Rheology of Complex fluids is to bring together young researchers and teachers from educational and R&D institutions, and expose them to the basic concepts and research techniques used in the study of rheological behavior of complex fluids. The lectures will be delivered by well-recognized experts. The book contents will be based on the lecture notes of the school.

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Complex Fluids in Biological Systems

This book serves as an introduction to the continuum mechanics and mathematical modeling of complex fluids in living systems. The form and function of living systems are intimately tied to the nature of surrounding fluid environments, which commonly exhibit nonlinear and history dependent responses to forces and displacements. With ever-increasing capabilities in the visualization and manipulation of biological systems, research on the fundamental phenomena, models, measurements, and analysis of complex fluids has taken a number of exciting directions. In this book, many of the world’s foremost experts explore key topics such as: Macro- and micro-rheological techniques for measuring the material properties of complex biofluids and the subtleties of data interpretation Experimental observations and rheology of complex biological materials, including mucus, cell membranes, the cytoskeleton, and blood The motility of microorganisms in complex fluids and the dynamics of active suspensions Challenges and solutions in the numerical simulation of biologically relevant complex fluid flows This volume will be accessible to advanced undergraduate and beginning graduate students in engineering, mathematics, biology, and the physical sciences, but will appeal to anyone interested in the intricate and beautiful nature of complex fluids in the context of living systems.

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Transport Phenomena in Complex Fluids

This book provides a thorough overview of transport phenomena in complex fluids, based on the latest research results and the newest methods for their analytical prediction and numerical simulation. The respective chapters cover several topics, including: a description of the structural features of the most common complex fluids (polymer and surfactant solutions, colloidal suspensions); an introduction to the most common non-Newtonian constitutive models and their relationship with the fluid microstructure; a detailed overview of the experimental methods used to characterise the thermophysical properties, bulk rheology, and surface properties of complex fluids; a comprehensive introduction to heat, mass, and momentum transport, and to hydrodynamic instabilities in complex fluids; and an introduction to state-of-the-art numerical methods used to simulate complex fluid flows, with a focus on the Smoothed Particle Hydrodynamics (SPH) and the Dissipative Particle Dynamics (DPD) techniques. Subsequent chapters provide in-depth descriptions of phenomena such as thermal convection, elastic turbulence, mixing of complex fluids, thermophoresis, sedimentation, and non-Newtonian drops and sprays. The book addresses research scientists and professionals, engineers, R&D managers and graduate students in the fields of engineering, chemistry, biology, medicine, and the applied and fundamental sciences.

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Microhydrodynamics and Complex Fluids

A self-contained textbook, Microhydrodynamics and Complex Fluids deals with the main phenomena that occur in slow, inertialess viscous flows often encountered in various industrial, biophysical, and natural processes. It examines a wide range of situations, from flows in thin films, porous media, and narrow channels to flows around suspended particles. Each situation is illustrated with examples that can be solved analytically so that the main physical phenomena are clear. It also discusses a range of numerical modeling techniques. Two chapters deal with the flow of complex fluids, presented first with the formal analysis developed for the mechanics of suspensions and then with the phenomenological tools of non-Newtonian fluid mechanics. All concepts are presented simply, with no need for complex mathematical tools. End-of-chapter exercises and exam problems help you test yourself. Dominique Barthès-Biesel has taught this subject for over 15 years and is well known for her contributions to low Reynolds number hydrodynamics. Building on the basics of continuum mechanics, this book is ideal for graduate students specializing in chemical or mechanical engineering, material science, bioengineering, and physics of condensed matter.

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Mathematical Modeling for Complex Fluids and Flows

Mathematical Modeling for Complex Fluids and Flows provides researchers and engineering practitioners encountering fluid flows with state-of-the-art knowledge in continuum concepts and associated fluid dynamics. In doing so it supplies the means to design mathematical models of these flows that adequately express the engineering physics involved. It exploits the implicit link between the turbulent flow of classical Newtonian fluids and the laminar and turbulent flow of non-Newtonian fluids such as those required in food processing and polymeric flows. The book develops a descriptive mathematical model articulated through continuum mechanics concepts for these non-Newtonian, viscoelastic fluids and turbulent flows. Each complex fluid and flow is examined in this continuum context as well as in combination with the turbulent flow of viscoelastic fluids. Some details are also explored via kinetic theory, especially viscoelastic fluids and their treatment with the Boltzmann equation. Both solution and modeling strategies for turbulent flows are laid out using continuum concepts, including a description of constructing polynomial representations and accounting for non-inertial and curvature effects. Ranging from fundamental concepts to practical methodology, and including discussion of emerging technologies, this book is ideal for those requiring a single-source assessment of current practice in this intricate yet vital field.

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Scattering Methods in Complex Fluids

A modern and experimental perspective on the developments in recent decades of the physics of complex liquids.

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Developments in the Flow of Complex Fluids in Tubes

This book is dedicated to the tube flow of viscoelastic fluids and Newtonian single and multi-phase particle-laden fluids. This succinct volume collects the most recent analytical developments and experimental findings, in particular in predicting the secondary field, highlighting the historical developments which led to the progress made. This book brings a fresh and unique perspective and covers and interprets efforts to model laminar flow of viscoelastic fluids in tubes and laminar and turbulent flow of single and multi-phase particle-laden flow of linear fluids in the light of the latest findings.

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Optical Rheometry of Complex Fluids

This book provides a self-contained presentation of optical methods used to measure the structure and dynamics of complex fluids subject to the influence of external fields. Such fields--hydrodynamic, electric, and magnetic--are commonly encountered in both academic and industrial research, and can produce profound changes in the microscale properties of liquids comprised of polymers, colloids, liquid crystals, or surfactants. Starting with the basic Maxwell field equations, this book discusses the polarization properties of light, including Jones and Mueller calculus, and then covers the transmission, reflection, and scattering of light in anisotropic materials. Spectroscopic interactions with oriented systems such as absorptive dichroism, small wide angle light scattering, and Raman scattering are discussed. Applications of these methods to a wide range of problems in complex fluid dynamics and structure are presented, along with selected case studies chosen to elucidate the range of techniques and materials that can be studied. As the only book of its kind to present a self-contained description of optical methods used for the full range of complex fluids, this work will be special interest to a wide range of readers, including chemical engineers, physical chemists, physicists, polymer and colloid scientists, along with graduate and post-graduate researchers.

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Thermodynamics of Complex Fluids for Chemical Enhanced Oil Recovery

Chemical enhanced oil recovery methods have significant potential to improve oil recovery after waterflooding. It is relatively easy to improve recovery in the lab under controlled conditions. However, field-scale implementations do not yield the same recovery results for a variety of reasons that include different mixing levels from the lab to the field, and also that species travel at different velocities. Moreover, the modeling of physicochemical phenomena, which are involved in the process, can be inaccurate or lack predictive capabilities. Such phenomena include phase behavior, viscosity, and reaction kinetics modeling. In this dissertation, we present modeling improvements and a better understanding of those physicochemical processes. The improvements will help to model accurately and to design successfully improved oil recovery scenarios. This dissertation presents the following research outcomes to model physicochemical phenomena involved in chemical enhanced oil recovery. Chapter I covers introductory remarks on chemical enhanced oil recovery. Chapter II focusses on the experimental study of alkali-cosolvent phase behavior using acidic crude oil. We study the possibility of using alkali for in situ surfactant generation, over costly synthetic surfactants. The chapter proposes a mechanism that explains the formation of water-in-oil macroemulsion, which is traditionally overlooked. Chapter III discusses an updated flash calculation algorithm with variable characteristic length in microemulsion phase. Chapter VI presents a microemulsion phase behavior equation of state algorithm that accounts for equilibrium K-values, and surfactant partitioning. For the first time, we propose equations to constrain the size of two-phase lobes. These constraints are based on constant K-value limiting conditions. Chapter V presents a compositional viscosity model for microemulsion systems. We present a 'viscosity map' approach that accounts for the percolation threshold locus in compositional space. The compositional aspect of microemulsion viscosity is typically overlooked in the literature. Chapter VI is focused on modeling the effects of reaction kinetics and dispersion during low salinity waterflooding. Reaction kinetics is typically ignored in reservoir simulation. We show that oil recovery is affected when reaction kinetics is included in the modeling, for example, recovery fronts are delayed based on the ratio of convection and reaction rates. Chapter VII concludes this dissertation. The common theme of this dissertation addresses the thermodynamics of complex fluids in the context of chemical enhanced oil recovery.

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Multiscale Modeling and Simulation in Science

Most problems in science involve many scales in time and space. An example is turbulent ?ow where the important large scale quantities of lift and drag of a wing depend on the behavior of the small vortices in the boundarylayer. Another example is chemical reactions with concentrations of the species varying over seconds and hours while the time scale of the oscillations of the chemical bonds is of the order of femtoseconds. A third example from structural mechanics is the stress and strain in a solid beam which is well described by macroscopic equations but at the tip of a crack modeling details on a microscale are needed. A common dif?culty with the simulation of these problems and many others in physics, chemistry and biology is that an attempt to represent all scales will lead to an enormous computational problem with unacceptably long computation times and large memory requirements. On the other hand, if the discretization at a coarse level ignoresthe?nescale informationthenthesolutionwillnotbephysicallymeaningful. The in?uence of the ?ne scales must be incorporated into the model. This volume is the result of a Summer School on Multiscale Modeling and S- ulation in Science held at Boso ¤n, Lidingo ¤ outside Stockholm, Sweden, in June 2007. Sixty PhD students from applied mathematics, the sciences and engineering parti- pated in the summer school.

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Basic Concepts for Simple and Complex Liquids

Presenting a unified approach, this book focusses on the concepts and theoretical methods that are necessary for an understanding of the physics and chemistry of the fluid state. The authors do not attempt to cover the whole field in an encyclopedic manner. Instead, important ideas are presented in a concise and rigorous style, and illustrated with examples from both simple molecular liquids and more complex soft condensed matter systems such as polymers, colloids, and liquid crystals.

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Droplet Wetting and Evaporation

Droplet Wetting and Evaporation provides engineers, students, and researchers with the first comprehensive guide to the theory and applications of droplet wetting and evaporation. Beginning with a relevant theoretical background, the book moves on to consider specific aspects, including heat transfer, flow instabilities, and the drying of complex fluid droplets. Each chapter covers the principles of the subject, addressing corresponding practical issues and problems. The text is ideal for a broad range of domains, from aerospace and materials, to biomedical applications, comprehensively relaying the challenges and approaches from the different communities leading the way in droplet research and development. Provides a broad, cross-subject coverage of theory and application that is ideal for engineers, students and researchers who need to follow all major developments in this interdisciplinary field Includes comprehensive discussions of heat transfer, flow instabilities, and the drying of complex fluid droplets Begins with an accessible summary of fundamental theory before moving on to specific areas such as heat transfer, flow instabilities, and the drying of complex fluid droplets

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Frustration and Self assembly in Complex Fluids

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The Structure and Rheology of Complex Fluids

The Structure and Rheology of Complex Fluids describes the microstructures of polymeric, colloidal, amphiphilic, and liquid crystalline liquids, and the relationship between microstructure and mechanical and flow properties. It provides illustrations, practical examples, and worked problems. This book can serve as both a textbook for a graduate course and a research monograph.

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Complex Fluids

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Hydrodynamics of Micro swimmers in Complex Fluids and Environments

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Trends in Colloid and Interface Science XVII

This volume contains a peer reviewed selection of the papers presented at the highly successful sixteenth meeting of the European Colloid and Interface Society which was held in Paris, France in September 2002 and highlights some of the important advances in this area. The topics covered include: Molecular self assemblies; Colloids and interfaces; Long range and/or weak interactions in interfacial systems; Original ways to probe colloidal systems; Colloids in biology. The volume is of interest to both academic and industrial scientists working with colloidal and interfacial systems in chemistry, physics and biology.

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Complex Fluid Flows in Microfluidics

This monograph contains expert knowledge on complex fluid-flows in microfluidic devices. The topical spectrum includes, but is not limited to, aspects such as the analysis, experimental characterization, numerical simulations and numerical optimization. The target audience primarily comprises researchers who intend to embark on activities in microfluidics. The book can also be beneficial as supplementary reading in graduate courses.

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