The Second Law of Thermodynamics and the Arrow of Time 107 irreversible
processes. It is a theory applicable to all systems in which the temperature is well
defined at every location. For example, the modern theory relates the rate of
change ...
Author: Dilip Kondepudi
Publisher: John Wiley & Sons
ISBN: 111837181X
Category: Science
Page: 552
View: 726
Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition presents a comprehensive introduction to 20th century thermodynamics that can be applied to both equilibrium and non-equilibrium systems, unifying what was traditionally divided into ‘thermodynamics’ and ‘kinetics’ into one theory of irreversible processes. This comprehensive text, suitable for introductory as well as advanced courses on thermodynamics, has been widely used by chemists, physicists, engineers and geologists. Fully revised and expanded, this new edition includes the following updates and features: Includes a completely new chapter on Principles of Statistical Thermodynamics. Presents new material on solar and wind energy flows and energy flows of interest to engineering. Covers new material on self-organization in non-equilibrium systems and the thermodynamics of small systems. Highlights a wide range of applications relevant to students across physical sciences and engineering courses. Introduces students to computational methods using updated Mathematica codes. Includes problem sets to help the reader understand and apply the principles introduced throughout the text. Solutions to exercises and supplementary lecture material provided online at http://sites.google.com/site/modernthermodynamics/. Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition is an essential resource for undergraduate and graduate students taking a course in thermodynamics.
This identification will form our bridge between the microscopic and
thermodynamic pictures of matter. We shall base our development on the
statistical mechanics of Gibbs. This is the foundation for all modern work based
on a microscopic ...
Author: Carl S. Helrich
Publisher: Springer Science & Business Media
ISBN: 3540854177
Category: Science
Page: 402
View: 556
Thermodynamics is not the oldest of sciences. Mechanics can make that claim. Thermodynamicsisaproductofsomeofthegreatestscienti?cmindsofthe19thand 20th centuries. But it is suf?ciently established that most authors of new textbooks in thermodynamics ?nd it necessary to justify their writing of yet another textbook. I ?nd this an unnecessary exercise because of the centrality of thermodynamics as a science in physics, chemistry, biology, and medicine. I do acknowledge, however, that instruction in thermodynamics often leaves the student in a confused state. My attempt in this book is to present thermodynamics in as simple and as uni?ed a form as possible. As teachers we identify the failures of our own teachers and attempt to correct them. Although I personally acknowledge with a deep gratitude the appreciation for thermodynamics that I found as an undergraduate, I also realize that my teachers did not convey to me the sweeping grandeur of thermodynamics. Speci?cally the s- plicity and the power that James Clerk Maxwell found in the methods of Gibbs were not part of my undergraduate experience. Unfortunately some modern authors also seem to miss this central theme, choosing instead to introduce the thermodynamic potentials as only useful functions at various points in the development.
Maybe it is a double-edged sword, as it also means a severe situation for modern
thermodynamics that after about a century of exploration the term “modern
thermodynamics” had not been well accepted. This may be due to some basic ...
Author: Jitao Wang
Publisher: Springer Science & Business Media
ISBN: 3642113494
Category: Science
Page: 279
View: 122
"Modern Thermodynamics- Based on the Extended Carnot Theorem" provides comprehensive definitions and mathematical expressions of both classical and modern thermodynamics. The goal is to develop the fundamental theory on an extended Carnot theorem without incorporating any extraneous assumptions. In particular, it offers a fundamental thermodynamic and calculational methodology for the synthesis of low-pressure diamonds. It also discusses many "abnormal phenomena", such as spiral reactions, cyclic reactions, chemical oscillations, low-pressure carat-size diamond growth, biological systems, and more. The book is intended for chemists and physicists working in thermodynamics, chemical thermodynamics, phase diagrams, biochemistry and complex systems, as well as graduate students in these fields. Jitao Wang is a professor emeritus at Fudan University, Shanghai, China.
Summary Thermodynamics enables us to answer questions such as “if the
pressure P of a given mass of an ideal gas changes, by how much does the
temperature T change?”. To do this, we need to have an appropriate
mathematical ...
Author: Dennis Sherwood
Publisher: Oxford University Press
ISBN: 0191085820
Category: Science
Page: 928
View: 802
Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.
Thermodynamics is like a forest. The tall trees in the center of the forest are the
laws of thermodynamics. They are surrounded by a thick underbrush of thorny
bushes. These bushes are the thermodynamic properties. Some are known by
their ...
Author: Robert T. Balmer
Publisher: Academic Press
ISBN: 9780080961736
Category: Science
Page: 825
View: 293
Modern Engineering Thermodynamics is designed for use in a standard two-semester engineering thermodynamics course sequence. The first half of the text contains material suitable for a basic Thermodynamics course taken by engineers from all majors. The second half of the text is suitable for an Applied Thermodynamics course in mechanical engineering programs. The text has numerous features that are unique among engineering textbooks, including historical vignettes, critical thinking boxes, and case studies. All are designed to bring real engineering applications into a subject that can be somewhat abstract and mathematical. Over 200 worked examples and more than 1,300 end of chapter problems provide opportunities to practice solving problems related to concepts in the text. Provides the reader with clear presentations of the fundamental principles of basic and applied engineering thermodynamics. Helps students develop engineering problem solving skills through the use of structured problem-solving techniques. Introduces the Second Law of Thermodynamics through a basic entropy concept, providing students a more intuitive understanding of this key course topic. Covers Property Values before the First Law of Thermodynamics to ensure students have a firm understanding of property data before using them. Over 200 worked examples and more than 1,300 end of chapter problems offer students extensive opportunity to practice solving problems. Historical Vignettes, Critical Thinking boxes and Case Studies throughout the book help relate abstract concepts to actual engineering applications. For greater instructor flexibility at exam time, thermodynamic tables are provided in a separate accompanying booklet. Available online testing and assessment component helps students assess their knowledge of the topics. Email
[email protected] for details.
Modern. Thermodynamics. In 1931, Lars Onsager (1903 1976) proposed the first
general relation in nonequilibrium thermodynamics: the ... In 1959 the term "
modern thermodynamics" had already been used in the summer program at MIT
2.1].
Author: Ji-Tao Wang
Publisher: Springer Science & Business Media
ISBN: 9783540428022
Category: Science
Page: 254
View: 848
This book introduces a new and successful concept for thermodynamics: nonequilibrium phase diagrams. This concept has been successfully applied to diamond synthesis. The book goes on to demonstrate how these diagrams lead to a complete new systematization of modern thermodynamics.
Studies of the Hurricane Evolution Based on Modern Thermodynamics.
Author: Chongjian Liu
Publisher:
ISBN:
Category: Science
Page:
View: 182
Studies of the Hurricane Evolution Based on Modern Thermodynamics.
Also reprinted from Van Wylen, G. J., Sonntag, R. E., 1986. Fundamentals of
Classical Thermodynamics, third ed. Wiley, New York, p. 688 (Table A. 9E).
Copyright © 1986 John Wiley 8 Sons. Reprinted by permission of John Wiley 8
Sons, lnc.
Author: Robert T. Balmer
Publisher: Academic Press
ISBN: 9780123850393
Category: Technology & Engineering
Page: 76
View: 221
Thermodynamic Tables to Accompany Modern Engineering Thermodynamics is a companion text to Modern Engineering Thermodynamics by Robert T. Balmer. It contains two Appendices—Appendix C features 40 thermodynamic tables, while Appendix D provides 6 thermodynamic charts. These charts and tables are provided in a separate booklet to give instructors the flexibility of allowing students to bring the tables into exams. This booklet is provided at no extra charge with new copies of Balmer's book. It may be purchased separately if needed.
Bimalendu Narayan Roy. Principles of Modern Thermodynamics Principles of
Modern Thermodynamics B N Roy Department of Physics.
Author: Bimalendu Narayan Roy
Publisher: CRC Press
ISBN:
Category: Science
Page: 569
View: 159
The intention is to provide a sound understanding of both the fundamental physical principles of thermodynamics and the more advanced concepts of the subject.
The historical development of thermodynamics -- Elements of probability theory -- Shannon's measure of information (SMI) -- Three theorems on Shannon's measure of information -- The entropy function of a classical ideal gas -- ...
Author: Arieh Ben-Naim
Publisher: World Scientific Publishing Company
ISBN: 9789813200753
Category: Science
Page: 355
View: 761
The historical development of thermodynamics -- Elements of probability theory -- Shannon's measure of information (SMI) -- Three theorems on Shannon's measure of information -- The entropy function of a classical ideal gas -- Thermodynamics of ideal gas -- The fundamental principles of thermodynamics -- The phase rule and phase diagrams -- Mixtures and solutions -- Chemical equilibrium -- Water and aqueous solutions
This book is a valuable compilation of topics, ranging from the basic to the most complex advancements in the field of thermodynamics. It explores the modern systems and principles introduced in this field.
Author: Nora Jonas
Publisher:
ISBN: 9781682855898
Category:
Page: 239
View: 263
This book is a valuable compilation of topics, ranging from the basic to the most complex advancements in the field of thermodynamics. It explores the modern systems and principles introduced in this field. Thermodynamics is the study of the relation of heat and temperature with forms of energy. It is based on four principal laws that define and characterize physical quantities. The technological progress over the years has fueled the advancements in the field of thermodynamics. The prevalent thermodynamic principles and concepts have applications across a range of fields such as chemical engineering, industrial ecology, physical chemistry, etc. The data collated in this book provides in-depth knowledge about the modern theories of thermodynamics. The extensive content herein will be helpful for those who want to broaden the expanse of their knowledge in this area of study.
Author:
Publisher:
ISBN:
Category:
Page:
View: 662
Author: Edward Armand Guggenheim
Publisher:
ISBN:
Category: Thermodynamics
Page: 206
View: 178
Author: Dilip Kondepudi
Publisher: Wiley
ISBN: 0470986492
Category: Science
Page: 516
View: 541
This is the first modern approach to thermodynamics written specifically for a first undergraduate course. It covers the fundamental formalism with some attention given to its history; describes basic applications of the formalism and continues with a number of additional applications that instructors can use according to their particular degree program – these chapters cover thermal radiation, biological systems, nano systems, classical stability theory, and principles of statistical thermodynamics. A wide range of examples appear throughout the book from biological, engineering and atmospheric systems. Each chapter contains a bibliography and numerous examples and exercises. An accompanying web site will provide students with information and links to data sources and other thermodynamics-related sites, and instructors will be able to download complete solutions to exercises.
5,600 Exam Prep questions and answers.
Author:
Publisher:
ISBN:
Category:
Page:
View: 631
Although mostly presumptive in the literature, such attempts should be formulated
with fundamental principles for modern thermodynamics. I have selected
structural changes and superconducting transitions for this book to discuss as
basic ...
Author: Minoru Fujimoto
Publisher: Springer Science & Business Media
ISBN: 9781441966889
Category: Science
Page: 236
View: 767
Originated from studies on steam engines, thermodynamics is formulated traditi- ally for homogeneous materials. Applying to condensed matters however, laws of thermodynamics have to be evaluated with respect to the structural detail. Foll- ing after Kirkwood’s chemical thermodynamics, the author’s attempt is to discuss lattice dynamics in crystalline states in light of the traditional laws. It is noted that lattice symmetry remains as implicit in crystalline states if assumed as homo- neous, whereas deformed crystals with disrupted symmetry are not necessarily stable and inhomogeneous, exhibiting mesoscopic properties. In this context, the lattice dynamics in uniform crystalline states should accordingly be revised. Although mostly presumptive in the literature, such attempts should be formulated with fundamental principles for modern thermodynamics. I have selected structural changes and superconducting transitions for this book to discuss as basic pheno- na in crystals in thermal environment. Born and Huang have laid ground for thermodynamics of crystalline states in their book Dynamical Theory of Crystal Lattices. They assumed, however, that order– disorder phenomena were independent from the lattice dynamics, and hence excluded from their book. On the other hand, new evidence indicates that the problem must be treated otherwise; the lattice does play a vital role in ordering processes. Accordingly, I was motivated to write about physics of crystal lattice in the light of Born–Huang’s principles, which constitutes my primary objective in this book.
The Thermodynamics of Irreversible Processes and Generalized Hydrodynamics
Byung Chan Eu. Clausius himself, of course ... The Carnot theorem plays an
indispensable role even in the modern thermodynamics. It characterizes in
essence ...
Author: Byung Chan Eu
Publisher: Springer Science & Business Media
ISBN: 0306480492
Category: Science
Page: 344
View: 458
Despite a long history of almost 180 years stretching back to the times of Carnot and, later, Clausius and Lord Kelvin, amongst others following him, the subject of thermodynamics has not as yet seen its full maturity, in the sense that the theory of irreversible processes has remained incomplete. The works of L. Onsager, J. Meixner, I. Prigogine on the thermodyn- ics of linear irreversible processes are, in effect, the early efforts toward the desired goal of giving an adequate description of irreversible processes, but their theory is confined to near-equilibrium phenomena. The works in recent years by various research workers on the extension of the aforem- tioned thermodynamic theory of linear irreversible processes are further efforts toward the goal mentioned. The present work is another of such efforts and a contribution to the subject of generalizing the thermodyn- ics of reversible processes, namely, equilibrium thermodynamics, to that of irreversible processes—non-equilibrium thermodynamics, without being restricted to linear irreversible processes. In this context the terms ‘far - moved from equilibrium’ is often used in the literature, and such states of macroscopic systems and non-linear irreversible phenomena in them are the objects of interest in this work. The thermodynamics of processes, either reversible or irreversible, is a continuum mechanical theory of matter and energy and their exchange between different parts of the system, and as such it makes no direct r- erence to the molecules constituting the substance under consideration.
Coleman , B. D. and J. Greenberg , Thermodynamics and the stability of fluid
motion . Arch . Rational Mech . Anal . 25 , 321-341 . Coleman , B. D. and M. E.
Gurtin , Thermodynamics with internal state variables . J. Chem . Phys . 47 , 597-
613 .
Author: Morton E. Gurtin
Publisher:
ISBN:
Category: Thermodynamics
Page: 78
View: 475
Emergence of Thermodynamic Behavior Within Composite Quantum Systems
Jochen Gemmer, Mathias Michel, Günter Mahler ... This gave rise to modern
thermodynamics. a theory the validity of which is beyond any doubt today. Its
results ...
Author: Jochen Gemmer
Publisher: Springer Science & Business Media
ISBN: 9783540229117
Category: Science
Page: 287
View: 467
This extended tutorial essay views thermodynamics as an incomplete description of quantum systems with many degrees of freedom. The main goal is to show that the approach to equilibrium - with equilibrium characterized by maximum ignorance about the open system of interest - neither requires that many particles nor is it a precise way of partitioning relevant for the salient features of equilibrium and equilibration. Moreover it is indeed quantum effects that are at work in bringing about universal thermodynamic behaviour of modestly sized open systems. Von Neumann`s concept of entropy thus proves to be much more widely useful than something to be feared, and far beyond truly macroscopic systems in equilibrium.
Although such modern thermodynamics is a mathematical theory established
mainly by mathematicians, this book is focused on non-mathematicians—
physicists, chemists and engineers. They are usually and typically studying
systems where ...
Author: Miloslav Pekař
Publisher: Springer Science & Business Media
ISBN: 3319025147
Category: Science
Page: 308
View: 202
In this book, Samohýl and Pekař offer a consistent and general non-equilibrium thermodynamic description for a model of chemically reacting mixtures. This type of model is frequently encountered in practice and up until now, chemically reacting systems (out of equilibrium) have rarely been described in books on non-equilibrium thermodynamics. Readers of this book benefit from the systematic development of the theory; this starts with general principles, going through the applications to single component fluid systems, and finishing with the theory of mixtures, including chemical reactions. The authors describe the simplest mixture model – the linear fluid – and highlight many practical and thermodynamically consistent equations for describing transport properties and reaction kinetics for this model. Further on in the book, the authors also describe more complex models. Samohýl and Pekař take special care to clearly explain all methodology and starting axioms and they also describe in detail applied assumptions and simplifications. This book is suitable for graduate students in chemistry, materials science and chemical engineering as well as professionals working in these and related areas.